Plastic Pyrolysis Process

Plastic pyrolysis process is an advanced chemical recycling process that breaks down plastic polymers at high temperatures under oxygen-free conditions, converting waste plastics into valuable pyrolysis oil and gases. This technology not only helps reduce reliance on landfilling and incineration but also provides alternative feedstocks for the energy and chemical industries. In this article, Beston Group will take you on an in-depth look at the core principles and practical value of plastic pyrolysis.

Technical Principles of Plastic Pyrolysis Process

Catalytic Pyrolysis Technology of Plastic Pyrolysis Plant

Regular Technology: Plastic Pyrolysis

  • Principle: Waste plastics are thermally decomposed at high temperatures under oxygen-deficient or oxygen-free conditions. The basic mechanism involves using heat to break the polymer chains of plastics, cracking large molecules into smaller ones and producing liquid oil, combustible gases, and a small amount of solid residue.
  • Product Features: Pyrolysis oil containing wax.
  • Current Application: Conventional pyrolysis is the most fundamental and widely applied process.

Extended Technology: Catalytic Plastic Pyrolysis

  • Principle: Building upon conventional pyrolysis, catalysts—such as zeolites—are introduced to improve reaction efficiency and product quality.
  • Product Features: High-quality pyrolysis oil.
  • Industrial Outlook: With continuous advancements in catalytic materials and process optimization, catalytic pyrolysis is increasingly becoming a key direction for the large-scale commercialization of plastic pyrolysis.
  • Advantages: Higher liquid oil yield with significantly improved oil quality. Lower energy consumption, enhancing economic feasibility. Reduced equipment clogging and minimized downtime losses.

Involved Equipment in Plastic Pyrolysis Process

To carry out plastic pyrolysis, a special machine called a plastic pyrolysis plant is used. It is built to withstand high temperatures and keep the process free of oxygen. This creates the right conditions for plastic waste to break down safely and turn into useful products.

Plastic Pyrolysis Machine-Continuous Type

Continuous Type: BLL-30

  • Large-scale choice: process 6,000 tons annually
  • 30 day continuous operation
  • High automation: two operators required
  • Policy support and incentives
  • Easy to get environmental compliance and project approval
Plastic Pyrolysis Machine-Batch Type

Batch Type: BLJ-16

  • Small-scale choice: process 3,000 tons annually
  • 1 furnace/day
  • 3 Configuration options
ModelBLL-30BLJ-16 WAXBLJ-16 CATBLJ-16 ULTRA
ManufacturerBESTONBESTONBESTONBESTON
Time to Market2025202220222022
Motor BrandChinese brandChinese brandChinese brandABB Explosion-proof
Suitable Raw MaterialsWaste plastics; Tires; Oil sludgeWaste plastic bales
(Max.0.9*0.9*1.6m)
Waste plastic bales
(Max.0.9*0.9*1.6m)
Waste plastics; Tires; Oil sludge
Input Capacity (Max.)Waste plastic pellets: 0.8-1.05t/h
Rubber powder: 1.25-1.5t/h
Oil sludge:1.8-2.3t/h
8-10t/batch8-10t/batchWaste plastic bales: 8-10t/batch
Whole tire <120cm or Tire blocks<15cm: 10-12t/batch
Sidewall removed tire: 15-16t/batch
Oil sludge: 16-18t/batch
Working MethodFully ContinuousBatchBatchBatch
Final Oil QualityPyrolysis oil
Pyrolysis oil with wax or naphtha
Pyrolysis oil with waxPyrolysis oil with naphthaPyrolysis oil
Pyrolysis oil with wax or naphtha
Reactor Material304/310S Stainless steel304 Stainless steel304 Stainless steel304 Stainless steel
Reactor Life Span (Years)5-85-85-85-8
Guarantee (Months)12121212
Delivery Time (Calendar Days)60-90606090
Land Space Required (L*W*H*m)70*20*1033*13*833*13*833*26*8
Packing20*6*3m in bulk+13*40HQ1*40FR+3*40HQ1*40FR+3*40HQ+1*20GP1*40FR+8*40HQ
Installation Period (Calendar Days)60-90454560

Plastic Pyrolysis Process Steps: Catalytic Pyrolysis Technology

01 Feeding

Feed plastic waste into plastic pyrolysis reactor. In the video, the batch plastic to oil machine adopts a hydraulic feeder. Remove the hydraulic feeder after feeding. The door must be closed and locked.

02 Preheating

Start the main reactor rotation and preheating. Wait for the main furnace to reach the desired temperature. The fuel can be diesel, natural gas, heavy oil or pyrolysis oil. To save fuel consumption, we design syngas recycling.

03 Catalytic Pyrolysis

When the main reactor’s temperature reaches about 100℃ after 2-3h, it begins to produce oil gas. The high-temperature flue gas generated during pyrolysis is heated in the jacket layer of the catalytic tower, and the oil gas passes through the catalytic tower.

04 Condensing and Pyrolysis Gas Treatment

Then high-temperature oil gas enters the vertical tube condenser, condenses into liquid oil, and enters the storage tank for storage. Non-condensable pyrolysis gas enters the water seal and is recycled for reactor heating. The excess pyrolysis gas enters the exhaust chamber for burning out.

05 Discharging

Close the burners after the reaction. The main reactor and the draft fan still operate normally. After 7-8h of natural cooling, the slag can be discharged by auto screw discharger and water-cooling discharger.

06 Flue Gas Dedusting

The high-temperature flue gas from the catalytic tower and the main reactor enters the flue condenser for cooling treatment and enters the spray tower for spraying dedusting. This gas is discharged through the chimney to the atmosphere, finally achieving EU environmental standards.

What Plastic Types Suit Plastic Pyrolysis Process?

The success of the plastic waste pyrolysis process relies heavily on selecting the right types of waste plastics as raw materials. Different plastics have unique chemical compositions, influencing pyrolysis efficiency, safety, and output.

Plastic Type for Plastic Pyrolysis Process

Recommend PE, PP, PS, and more

These plastics are highly recommended for pyrolysis due to their high oil yield during decomposition.

Refuse Chlorinated Plastic (PET)

Its pyrolysis releases hydrogen chloride gas which corrodes equipment. The produced pyrolysis oil may emit carcinogenic dioxins when combusted.

Refuse Oxygenated Plastic (PVC)

Its pyrolysis does not yield oil and Releases oxygen which poses a safety hazard.

What Is the Output of Plastic Pyrolysis Process?

The pyrolysis process for plastics focuses on producing liquid pyrolysis oil, which can be used as an alternative to traditional fossil fuels or further refined to diesel or gasoline. Oil yield for reference:

Oil Yield of Plastic Pyrolysis Process

What Factors Affect Plastic Pyrolysis Process?

Several factors significantly influence the efficiency and output of the plastic pyrolysis process. Optimizing these factors helps maximize the yield of expected end products and minimize environmental impact. Key considerations include the following:

Pyrolysis Temperature

  • Meaning: the heat level inside the reactor during pyrolysis, typically measured at °C.
  • Influence: It significantly influences pyrolysis efficiency and end product type. Higher temperatures accelerate reactions, but excessively high temperatures can cause unwanted side reactions and energy inefficiencies.
  • Example: To get a high oil yield, recommend 300-400℃. To maximize syngas yield, recommend 500-1300℃.

Heating Rate

  • Meaning: the speed at which the temperature increases during the plastic pyrolysis process, typically expressed at °C/min.
  • Influence: A high heating rate typically results in a higher yield of combustible gas and less solid residue. A slower heating rate may bring more liquid fuel oil and solids.

Reactor Pressure

  • Meaning: the force exerted by gases or vapors on a unit area within a reactor, typically expressed in pascals (Pa) or atmospheres (atm).
  • Influence: Pressure inside the reactor also affects the composition of the products. Maintaining proper intracranial pressure is also a means to ensure the safety of plastic pyrolysis process steps.
  • Example: Beston Group’s pyrolysis plant maintains a micronegative pressure in the reactor to ensure safety.

Residence time

  • Meaning: the average amount of time that reactants spend in a reactor, typically measured in seconds (s) or minutes (min).
  • Influence: Balancing residence time is important – too short may result in incomplete conversion, while too long may lead to the formation of undesirable by-products. A shorter residence time typically produces more liquid products. A longer residence time leads to more gas formation.

Reactor Design

  • Meaning: the different kinds of equipment or vessels used for conducting pyrolysis reactions. Common types include fixed-bed reactor, fluidized-bed reactor, rotary kiln reactor, and more.
  • Influence: Different types of reactors have varying mixing and heat transfer characteristics, which can impact the efficiency of the pyrolysis process and the distribution of products.
  • Example: Beston Group utilizes rotary kiln reactor design, which offers uniform reaction and high thermal efficiency.

Catalysts

  • Meaning: a substance that accelerates a decomposition reaction, usually not consumed in the process, remaining unchanged after the reaction.
  • Influence: An appropriate catalyst can increase the yield of desired products and reduce the overall energy input of the process. The proportion of the same catalyst (the ratio of catalyst to plastic) can also have different effects on pyrolysis.
  • Example: The ZSM-5 catalyst can reduce impurities like solid residues, sulfur, nitrogen, and phosphorus in the liquid oil produced. For example, when the ratio of kaolin to WPP plastic is 1:2, the oil yield reaches its highest at 80.75 wt%.

Pyrolysis Paves the Way for Plastic Sustainability

The plastic pyrolysis process represents more than just a technological pathway—it embodies a vision for a circular economy where waste is not the end but the beginning of new resources. It bridges today’s environmental challenges with tomorrow’s sustainable industries. As research deepens and applications expand, pyrolysis may well become a cornerstone of how societies rethink waste and reshape the future of materials. For professional guidance, please consult Beston Group.

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